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As you have seen in the lab, precipitation
reactions have a characteristic "look" to them. A solid
that was not present before appears in the solution. This solid
is one (or sometimes both) of the products of the reaction. When
no solid appears, no reaction has taken place.
To understand what is happening on the level of
atoms it is important to remember that the reactants are ionic
compounds and act as electrolytes in water. That means ions are
present. So a solution of silver nitrate doesn't actually contain
AgNO3, but rather contains Ag+ and NO3-
ions. A conductivity test confirms the presence of these ions.
Thus when silver nitrate solution is added to,
let's say, sodium chromate solution (containing Na+
and CrO42- ions), the reaction which occurs
takes place among the ions, not the groups of atoms written as
formulas on the containers. This is true for all precipitation
reactions.  
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