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In the case of ionic bonding since metals
typically have relatively good shielding and lower ionization
energies, outer electrons are more easily removed (i.e.,
oxidation). Non-metals have relatively poor shielding and higher
electron affinities. That means they are capable of accepting
additional electrons (i.e., reduction).
Another way to look at that is to examine typical electron configurations for such elements, say, sodium and chlorine: Both of these configurations are one electron
different from a full s-p complement of 8 electrons. If the
sodium loses one electron and the chlorine gains one the
resulting ions will each have eight electrons in the highest
occupied energy level (an "octet"). We can represent
this in another way using a diagrammatic form of the electron
configuration called an "orbital diagram". |
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