Bond energies are limited in
their application for the reasons discussed earlier. They were:
- values are for gases only
- many values are averages
These are serious drawbacks if
you want energy information about most reactions. Fortunately
there is another way.
Remember in our definition of enthalpy (H) we said it was a "state function".
The net enthalpy change (DH--which is the only kind of enthalpy
quantity we can measure) is independent of path. What
does this mean?
If a process can be carried out
in a single step, the enthalpy change for that step will be the
same as for a series of steps which add up to give the same
overall step.  
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