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Lewis structures may give us
insight into how electrons might be shared in covalent bonding but
they fail in one very important aspect of understanding molecular
structure: most
molecules are not "flat".
At first thought this may seem
a minor problem. But because bonding electrons are usually not
shared equally except in the simplest molecules So how does one get from a two-dimensional Lewis diagram to a three-dimensional picture of molecular structure? One of the early proposals to explain the geometries of molecules was proposed by Linus Pauling. His main idea, that in molecules the atomic orbitals we have studied "hybridize" into new orbitals with specific shapes, is something we will look at a little later. |
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