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VSEPR all wet?
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As a simple case in point the
water molecule should assemble by sharing p-orbital electrons
from the oxygen atom with s-orbital electrons from the hydrogen
atoms.  But the p-orbitals in the oxygen should be at 90o
angles to one another. Yet the bond angles in water are about 104.5o.
Something similar should happen in the ammonia molecule, but
there the bond angles are closer to 107.5o.
So the VSEPR model treats
electron pairs as little domains on the valence level of the
central atom that move around as needed to minimize repulsions
but bear little resemblance to the Schrödinger orbitals we have
learned about. That's where hybridization comes in. Next time.
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