Lattices
Vibrations in solids
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In the solid state most atoms,
ions and molecules are confined in more or less regular 3-dimensional
structures which are called lattices  . Crystalline solids fit this
description and most solids are crystalline. Amorphous solids (such
as glass) have little local structure and the atoms or molecules
of such solids are "arranged" more like a very viscous
liquid.
With either type of solid, the
particles are restricted greatly in motion. Energy absorbed as
the temperature is raised goes into small vibrations of the
particles in the vicinity of the lattice points  . The rigidity of the crystal structure
will thus be related to the entropy of the solid at different
temperatures since little energy can be dispersed by such small
movements and so we find that harder solids tend to have lower
entropies. The specifc
heats of very hard solids also tend to be low because of the
limited ways in which heat energy can be dispersed as particle
motion.
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