The decomposition of the organic compound acetaldehyde can be expressed by the reaction below:

CH3CHO CH4 + CO

The rate constants for the reaction at various temperatures are found in the table below:






k

T (K)

ln k

1/T

0.011

700

-4.51

0.00143

0.035

730

-3.35

0.00137

0.105

760

-2.25

0.00132

0.343

790

-1.07

0.00127

0.789

810

-0.237

0.00123


The value of the slope on this graph is equal to -Ea/R. That means we can find Ea in this way:

Ea = -8.31 J/mol·K (-21600/K) = 1.79 x 105 J/mol or 179 kJ/mol