The decomposition of the organic compound acetaldehyde can be expressed by the reaction below:
CH3CHO → CH4 + CO
The rate constants for the reaction at various temperatures are found in the table below:
k |
T (K) |
ln k |
1/T |
0.011 |
700 |
-4.51 |
0.00143 |
0.035 |
730 |
-3.35 |
0.00137 |
0.105 |
760 |
-2.25 |
0.00132 |
0.343 |
790 |
-1.07 |
0.00127 |
0.789 |
810 |
-0.237 |
0.00123 |
The value of the slope on this graph is equal to -Ea/R. That means we can find Ea in this way:
Ea = -8.31 J/mol·K (-21600/K) = 1.79 x 105 J/mol or 179 kJ/mol