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These various little experiments
with an aqueous system illustrate some rate behavior with common
factors such as concentration, temperature and catalysts. There
are other factors as well which we mentioned in class. In
reactions where solids are involved surface area is certainly an
important factor. Subdividing the solid (e.g. grinding it to a
powder) is a way of exposing more surface to collisions.
Predictably, this generally results in an increase in reaction
rate.
When gases are involved pressure
is likewise an important factor with behavior analogous to
solution concentration. High pressure forces molecules closer to
one another and as the opportunity for collision increases, so
too (generally) does the rate.
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