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Once equlibrium has been reached, the reaction continues to occur, but with equal rate in opposite directions. This results in constant macroscopic properties and it "appears" that the reaction has stopped. But on the molecular level change continues. That is why the condition is sometimes called "dynamic equilibrium". The relative amounts of products and reactants
present at equilibrium under specified conditions are an
indicator of the extent of
reaction (i.e., "how far" things
went before equibrium was achieved). It has been found
experimentally that a certain ratio for the concentrations of
reactants and products will be constant for fixed conditions in a
particular reaction system. Generally the larger Keq, the more spontaneous a reaction is and the more product there will be at equilibrium.
Comparing equilibrium
constants for different reactions, however, is tricky business.
The law of mass action describes how equilibrium constants are
written from balanced equations. |
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