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A final thought: why does equilibrium happen in some processes and not in
others? Theoretically all reactions are
reversible. Practically speaking many are not. Those which are
have moderate positive or negative standard free energy changes (roughly
in the -60 to +60 kJ/mol range). These ΔGo values depend,
of course, on the enthalpy and entropy changes that occur during
the reactions. When TΔSo is similar in magnitude and sign to ΔHo then
the reaction is likely to reach equilibrium rather than proceed
to completion under standard conditions since at equilibrium:
0 = ΔG = ΔH - TΔS
The fact that equilibrium conditions can be expressed in this way leads to our next topic: how to manipulate equilibrium to obtain different amounts of reactants and products.
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