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All of these ideas taken
together make up what is known as LeChâtelier's Principle which states that any
change made to a system at equilibrium will cause a shift in
equilibrium that tends to counteract that change.
Each of the factors examined in this experiment
affects the rate of reaction. One additional factor has been
omitted: catalysts.
Catalysts speed up the rate of reactions by
lowering the activation energy requirement. But this happens for
both the forward and reverse reactions so there is no net effect.
Another way to think about the behavior of catalysts is in terms
of the free energy change. The balanced equation for a reaction
is the same with or without the catalyst. Therefore the free
energy change is the same with or without the catalyst. That
means the extent of spontaneity has not changed.
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