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DGo = -RT ln Kc
Among other things
this relationship reveals what Kc alone cannot. For
example, larger equilibrium constants generally mean more
products and fewer reactants at equilibrium. But it is difficult
to compare equilibrium constants which have different exponents.
Standard free energy values, on
the other hand, can be easily compared. Reactions with negative
standard free energies "favor" products at least a
little at equilibrium. The more negative, the more products.
Negative standard free energies correspond to Kc
values which are greater than 1. Positive standard free energies
correspond to Kc values which are less than 1. |