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Brønsted says...
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That means there is a very small
amount of H+ present at all times. These hydrogen ions
are strongly attracted to acetate ions--that is why acetic acid
is a weak acid. So when these ions encounter one another
in solution they will likely recombine:
CH3COO-(aq)
+ H+(aq) CH3COOH(aq)
This equilibrium favors the
product (remember, the acid is weak). But as H+
ions are gobbled up by the acetate ions, the equilibrium in water
is affected. In order to restore equilibrium, more water
molecules must dissociate:
H2O(ℓ) H+(aq) + OH-(aq)
The result is a
small excess of OH- in the mixture. It's basic! A similar argument can be used to show why solutions
of weak base cations are acidic but it's a stretch without
resorting to Brønsted  .
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