Brønsted says...



That means there is a very small amount of H+ present at all times. These hydrogen ions are strongly attracted to acetate ions--that is why acetic acid is a weak acid. So when these ions encounter one another in solution they will likely recombine:
CH3COO-(aq) + H+(aq) CH3COOH(aq)
This equilibrium favors the product (remember, the acid is weak). But as H+ ions are gobbled up by the acetate ions, the equilibrium in water is affected. In order to restore equilibrium, more water molecules must dissociate:

H2O(ℓ) H+(aq) + OH-(aq)

The result is a small excess of OH- in the mixture. It's basic! A similar argument can be used to show why solutions of weak base cations are acidic but it's a stretch without resorting to Brønsted .