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So in the part of drop where oxygen is most plentiful (oxygen from the air is constantly colliding with the drop surface) the reduction of oxygen makes the solution basic. Careful observation at the
interface between the pink outer region and the inner blue region
also reveals something about the corrosion process. Initially a
cloudy white or very pale green area slowly develops between the two
colored regions of the drop. Left undisturbed for some time this
interface area gradually takes on a pale orange color. Since the corrosion process is
clearly electrochemical in nature it should seem logical that ion
concentration will affect it. We see this most vividly in the HCl
but that extensive corrosion is essentially an equilibrium effect
since HCl will consume OH- and "pull" the
reaction forward. There is, however, a clear
difference between the behavior of distilled water, tap water and
sodium chloride solution. In that order they contain increasing
concentrations of ions of various types. |
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