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In the CuBr2
cell no gases are produced.  The solution contains Cu2+,
Br- and H2O. Since the visual evidence suggests copper metal and liquid bromine,
it is likely that these elements have smaller oxidation and
reduction potentials than water itself. A check of the SRP table
confirms this.  
When electricity
is passed through the KI solution the indicators show that the
cathode side becomes basic as a gas is produced.  Since potassium
ions could not be reduced to form a gas, this is probably
hydrogen. As we saw before, reducing neutral water produces
hydrogen gas and hydroxide ions. In any case, even if potassium could
form it reacts so violently with water it is not going to be
around to look at!
At the anode the
starch turns dark blue/black and yellowish material appears
around the electrode. This is certainly not oxygen (not even in L.A.!).
Iodine reacts with starch as described and we've observed its
color in aqueous solution before.  
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