Cobalt(II) chloride

 


Working it out

Comparing notes

In each of the examples so far there is a pattern. The criterion for predicting the products of the electrolysis comes down to which processes (one oxidation, one reduction) require the least voltage. On the SRP table that creates a predictable situation. Any substance which is reducible must be above the reduction of water (-0.83 V) in order to react instead of water. Any substance which is oxidizable must be below the oxidation of water (+1.23 V) in order to react instead of water.

With that in mind, we can see why cobalt metal is produced at the cathode in the CoCl2 cell instead of hydrogen gas.

But what about the anode reaction? A gas is produced which bleaches green food color. If you have a sensitive nose you might have recognized the gas as chlorine and not oxygen. How can this be?