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How it's done
It's the law
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In every electrochemical
process, whether spontaneous or not, a certain amount of electric
charge is transferred during the oxidation and reduction. The
half-reactions we have written for electrode processes include
the electrons which carry that charge. It is possible to measure
the rate at which the charge is transferred with a
device called an ammeter.
An ammeter measures the current
flowing through a circuit. The units of current are amperes (A) (amps, for short). Unlike a voltmeter,
ammeters allow electrons to pass and essentially "clock"
them as they go by.  The amount of electric charge which has
passed through the circuit can then be calculated by a simple
relationship:
Charge = current
x time OR Coulombs = amps
x seconds
This enables us to connect reaction
stoichiometry to electrical measurements. The principles
underlying these relationships were worked out in the first half
of the 19th century by the English scientist, Michael
Faraday. 
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